In this paper, we present the luminescent properties of Tm3+∕Ho3+ co-doped new glass. A series of silicategermanate glass was prepared by the conventional melt-quenching method. In the Tm3+∕Ho3+ co-doped silicategermanate glass, a strong emission of 2 μm originating from the Ho3+:5I7 → 5I8 transitio